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DnrK is a homolog of RdmB (52% sequence identity) that catalyzes methylation at O-4 of carminomycin (133) yielding daunorubicin (134), 202 which is a powerful chemotherapeutic agent and close structural analog of β-rhodomycin (126) (Fig

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The ROS release is involved in major cellular signaling pathways and allows the transmission of extracellular stimuli and changes in cell physiology by modulating the transcription of some genes or by post-transcriptional modulation